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Electron Correlation Dynamics (Cambridge Monographs on Atomic, Molecular and Chemical Physics)

Electron Correlation Dynamics (Cambridge Monographs on Atomic, Molecular and Chemical Physics)

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J. H. McGuire
Cambridge University Press
Edition: Digitally Printed 1st Pbk. Version, 8/21/2008
EAN 9780521018593, ISBN10: 0521018595

Paperback, 304 pages, 24.4 x 17 x 1.8 cm
Language: English

This graduate/research level text introduces the theory of multi-electron transitions in atomic, molecular and optical physics, emphasising the emerging topic of dynamic electron correlation. The book begins with an overview of simple binomial probabilities, classical scattering theory, quantum scattering and correlation, followed by the theory of single electron transition probabilities. Multiple electron transition probabilities are then treated in detail. Various approaches to multiple electron transitions are covered including the independent electron approximation, useful statistical methods and perturbation expansions treating correlation in both weak and strong limits. The important topic of the dynamics of electron correlation is a central theme in this book. The text contains a comprehensive summary of data for few and many-electron transitions in atoms and molecules, including transitions on different atomic centres, fast ion-atom and electron-atom interactions, and recent observations using synchrotron radiation. Emphasis is given to methods that may be used by non-specialists.

Preface
1. Introduction
2. Single electron–electron transition probabilities
3. Formulation of multi-electron transition probabilities
4. Independent electron approximation
5. Statistical methods
6. Correlated multi-electron–electron transition probabilities
7. Perturbation expansions
8. Projectiles carrying electrons
9. Reactions with photons
10. Relations between charged particle and photon reactions
Appendices
References.

'It makes for good reading with easy introductions before hard-nosed review of the latest concepts. I unreservedly and warmly recommend the above text as being a highly stimulating 'good read'.' D. Crothers, Contemporary Physics