Thermodynamics of Natural Systems: Theory and Applications in Geochemistry and Environmental Science
Cambridge University Press
Edition: 3, 4/27/2017
EAN 9781107175211, ISBN10: 1107175216
Hardcover, 428 pages, 25.4 x 19.3 x 2.3 cm
Language: English
Originally published in English
Thermodynamics deals with energy levels and energy transfers between states of matter, and is therefore fundamental to all branches of science. This new edition provides an accessible introduction to the subject, specifically tailored to the interests of Earth and environmental science students. Beginning at an elementary level, the first four chapters explain all necessary concepts via a simple graphical approach. Throughout the rest of the book, the author emphasizes the importance of field observations and demonstrates that, despite being derived from idealized circumstances, thermodynamics is crucial to understanding ore formation, acid mine drainage, and other real-world geochemical and geophysical problems. Exercises now follow each chapter, with answers provided at the end of the book. An associated website includes extra chapters and password-protected answers to additional problems. This textbook is ideal for undergraduate and graduate students studying geochemistry and environmental science.
Preface
1. What is thermodynamics?
2. Defining our terms
3. The First Law of Thermodynamics
4. The Second Law of Thermodynamics
5. Getting data
6. Some simple applications
7. Solutions
8. Fugacity and activity
9. The equilibrium constant
10. Rock-water systems
11. Redox reactions
12. Phase diagrams
13. Affinity and extent of reaction
Appendix A. Constants and numerical values
Appendix B. Standard state properties
Appendix C. Answers to exercises
References
Index
Online material
real solutions
The phase rule
Equations of state
Solid solutions
Electrolyte solutions
The Van't Hoff equilibrium box
Topics in mathematics.